Surface modification of layered zirconium phosphates: a novel pathway to multifunctional materials.

@article{Mosby2014SurfaceMO,
  title={Surface modification of layered zirconium phosphates: a novel pathway to multifunctional materials.},
  author={Brian M Mosby and Agust{\'i}n D{\'i}az and Abraham Clearfield},
  journal={Dalton transactions},
  year={2014},
  volume={43 27},
  pages={
          10328-39
        }
}
The intercalation of inorganic layered materials has resulted in a wide range of applicability. In such cases the applicability of the material is largely dependent upon the species intercalated within the layer, and the layered material acts largely as a host. Recently, the surface modification of inorganic layered materials has been investigated and it has been shown that the exterior layers can be exclusively functionalized. The advent of surface chemistry allows for the synthesis of… 
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Combination of intercalation and surface modification in layered zirconium phosphates: investigation of surface stability and reactivity.
TLDR
In both cases, the contents of the interlayer were found to impact the reactivity of the surface and stability of covalently attached surface groups, with higher interlayer loadings leading to decreased stability and reactsivity of surface phosphates.
Minimalistic Liquid-Assisted Route to Highly Crystalline α-Zirconium Phosphate.
TLDR
Key features of this minimal solvent synthesis are the excellent yields obtained with high atom economy under mild conditions and ease of scalability.
Tailoring the Growth of Nanosized α-Zirconium Phosphate.
TLDR
This modified synthesis method of nanosized α-ZrP offers an alternate means to tune the size and morphology of the nanosization α-zirconium phosphate for broad applications.
Synthesis and Performance of Functionalized α-Zirconium Phosphate Modified with Octadecyl Isocyanate
The α-zirconium phosphate (α-ZrP) and hydrophobically modified α-zirconium phosphate (α-ZrP-I) were prepared. The grafting of octadecyl isocyanate was confirmed by Fourier transform infrared (FTIR)…
Surface modification of layered zirconium phosphate with PNIPAM.
A new method was reported to modify layered zirconium phosphate (ZrP) with thermoresponsive polymer PNIPAM (poly N-isopropylacrylamide). PNIPAM was proved to be covalently grafted onto ZrP. (60)Co…
The Nature of Interactions and UV-Induced Response within α-Zirconium Phosphate Intercalation Compounds with Azobenzenes
TLDR
Low density of molecules in the ZBCnA samples, allowed the effective, fast, and reversible isomerization of azobenzene, whereas the ZpA sample did not react to the UV irradiation because of the steric hindrance of tightly packed molecules.
Preparation, luminescence and photofunctional performances of a hybrid layered gadolinium-europium hydroxide
Modification of α-Zirconium Phosphate Synthesis - Effects of Crystallinity and Acidity on Eu(III) and Am(III) Ion Exchange
The aim of an ongoing study is to develop ion exchange materials to be used in low pH in mineral acids for the uptake and separation of trivalent lanthanides and actinides. We present material…
Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility.
For the first time, functional carboxylic acid (-COOH) groups protruding on both sides of zincophosphate sheets are prepared, leading to a unique surface-active lamellar material characterized by…
Functionalization of α-ZrP by 1,2-Epoxypropane for Further Modification
To prepare alpha zirconium phosphate (α-ZrP) with high interlayer distance, grafting ratio and thermal stability, 1,2-epoxypropane was used to modify α-ZrP as the epoxy group reacting with P-OH on…
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