Surface melting and crystallization behavior of polyhydroxyalkanoates studied by attenuated total reflection infrared spectroscopy

@inproceedings{Padermshoke2004SurfaceMA,
  title={Surface melting and crystallization behavior of polyhydroxyalkanoates studied by attenuated total reflection infrared spectroscopy},
  author={Adchara Padermshoke and Yukiteru Katsumoto and Harumi Sato and Sanong Ekgasit and Isao Noda and Yukihiro Ozaki},
  year={2004}
}
The surface melting and crystallization behavior of two biodegradable polyesters, poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (P(HB-co-HHx)) (HHxZ12 mol%) and poly(3-hydroxybutyrate) (PHB), were investigated by using attenuated total reflection (ATR) and transmission infrared (IR) spectroscopy coupled with the generalized two-dimensional (2D) correlation analysis. IR bands in the C]O stretching vibration region were analyzed to explore the changes in crystallinity at the surface and those in… CONTINUE READING

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