Surface-induced phase transition of asymmetric diblock copolymer in selective solvents.

@article{Wang2006SurfaceinducedPT,
  title={Surface-induced phase transition of asymmetric diblock copolymer in selective solvents.},
  author={Rong Wang and Zhibin Jiang and Yeng-Long Chen and G B Xue},
  journal={The journal of physical chemistry. B},
  year={2006},
  volume={110 45},
  pages={22726-31}
}
Surface-induced phase transition of asymmetric diblock copolymer in selective solvents is first theoretically investigated by using the real-space version of self-consistent field theory (SCFT). By varying the distance between two parallel hard surfaces (or the film thickness) W and the block copolymer concentration f(p), several morphologies are predicted and the phase diagram is constructed. Self-assembly morphologies of the diblock copolymer in dilute solution are found to change… CONTINUE READING

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Polymers in Confined Environments

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