Supercritical fluid Thermodynamics from equations of state

  title={Supercritical fluid Thermodynamics from equations of state},
  author={Vincent Giovangigli and Lionel MATUSZEWSKI},
Supercritical multicomponent fluid thermodynamics are often built from equations of state. We investigate mathematically such a construction of a Gibbsian thermodynamics compatible at low density with that of ideal gas mixtures starting from a pressure law. We further study the structure of chemical production rates obtained from nonequilibrium statistical thermodynamics. As a typical application, we consider the Soave-Redlich-Kwong cubic equation of state and investigate mathematically the… CONTINUE READING