Superbases for organic synthesis

@article{Schlosser1988SuperbasesFO,
  title={Superbases for organic synthesis},
  author={Manfred Schlosser},
  journal={Pure and Applied Chemistry},
  year={1988},
  volume={60},
  pages={1627 - 1634}
}
  • M. Schlosser
  • Published 1 January 1988
  • Chemistry
  • Pure and Applied Chemistry
Abstract 

Enantioselective syntheses with titanium carbohydrate complexes. Part 7. Enantioselective allyltitanation of aldehydes with cyclopentadienyldialkoxyallyltitanium complexes

The preparation, analysis, and reactions of novel, highly stereoselective cyclopentadienyldialkoxyallyltitanium reagents, available in both enantiomeric forms, are described. Chiral

Cyclopropenimine Superbases: Competitive Initiation Processes in Lactide Polymerization.

Model studies and comparative experiments with guanidine and phosphazene catalysts revealed the subtle influence of the nature of the superbase on competitive initiation processes.

Pyridine elaboration through organometallic intermediates: regiochemical control and completeness.

This approach relies on organometallic methods, which are both efficacious and extremely flexible as far as the substitution site and the product structure are concerned (86 references).

Macromers by carbocationic polymerization

SummaryThis communication describes the synthesis of two novel CH2=CH-O-headed polyisobutylene (PIB)-based macromers: and The syntheses were worked out by the help of model experiments and

A New Enantioselective Synthesis of the Aminodihydroisocoumarin Moiety of AI-77-B

The aminodihydroisocoumarin moiety of AI-77-B, a gastroprotective substance isolated from Bacillus pumilus AI-77, has been prepared from a convenient chiral synthon of L-erythrose by combination of
...

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By the way, the superbase also metalates N,N,N:N’-tetramethylethyleneamine (yields of derivatives up to 45%, L

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