Suicide nucleophilic attack: reactions of benzohydroxamate anion with bis(2,4-dinitrophenyl) phosphate.

Abstract

The reaction between the benzohydroxamate anion (BHO(-)) and bis(2,4-dinitrophenyl)phosphate (BDNPP) has been examined kinetically, and the products were characterized by mass and NMR spectroscopy. The nucleophilic attack of BHO(-) follows two reaction paths: (i) at phosphorus, giving an unstable intermediate that undergoes a Lossen rearrangement to phenyl… (More)
DOI: 10.1021/jo9007354

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@article{Orth2009SuicideNA, title={Suicide nucleophilic attack: reactions of benzohydroxamate anion with bis(2,4-dinitrophenyl) phosphate.}, author={Elisa S. Orth and Pedro L F da Silva and Renata da Silva Mello and Clifford A. Bunton and Humberto M S Milagre and Marcos Nogueira Eberlin and Haidi Dalida Fiedler and Faruk Nome}, journal={The Journal of organic chemistry}, year={2009}, volume={74 14}, pages={5011-6} }