Substrate Binding by a Parallel Metal Sheet Sandwich Complex: A Unique Role of an Additional Metal Atom.
@article{Ishikawa2017SubstrateBB, title={Substrate Binding by a Parallel Metal Sheet Sandwich Complex: A Unique Role of an Additional Metal Atom.}, author={Yuki Ishikawa and Koji Yamamoto and Tetsuro Murahashi}, journal={Angewandte Chemie}, year={2017}, volume={56 5}, pages={ 1346-1350 } }
A unique metal addition to the edge of a triangular palladium sandwich cluster is reported. While the edge coordination sites of a parallel sandwich complex are narrow because of two sterically encumbering π-ligands, association of an additional metal atom to a metal sheet gives a wider coordination site. It was proved that the additional metal atom plays a crucial role in binding of cyclopentadienyl by a Pd3 sheet sandwich complex.
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