Substitution Reactions of Aluminum Organoamide Complexes [Al(μ-NR2)nCl3-n]2 (R = Et, iPr; n ≤ 3) with LiNR‘R‘‘ (R‘ = R‘‘ = iPr, Et; R‘ = H, R‘‘ = iPr): Crystal Structure of [Al(μ-NEt2)(NiPr2)X]2 (X = Cl, H) and AlCl3(NiPrH2)2{Al(NH3)(NH2)[Al(NiPrH)(NiPr)Cl]2}2

@inproceedings{Chang1997SubstitutionRO,
  title={Substitution Reactions of Aluminum Organoamide Complexes [Al(μ-NR2)nCl3-n]2 (R = Et, iPr; n ≤ 3) with LiNR‘R‘‘ (R‘ = R‘‘ = iPr, Et; R‘ = H, R‘‘ = iPr): Crystal Structure of [Al(μ-NEt2)(NiPr2)X]2 (X = Cl, H) and AlCl3(NiPrH2)2\{Al(NH3)(NH2)[Al(NiPrH)(NiPr)Cl]2\}2},
  author={Chung-Cheng Chang and Mung-Dar Li and Michael Y. Chiang and Shie-Ming Peng and Yu Wang and Gene-Hsiang Lee},
  year={1997}
}
As part of our ongoing study of different substituents of Al2N2 ring systems, the synthesis, structural characterization, and spectroscopic studies on several amido derivatives of four-coordinated aluminum are described. The compounds Al2(NEt2)2(NiPr2)2Cl2, 1, Al2((NiPr2)4Cl2, 2, Al((NiPr2)3, 3, Al(NEt2)3, 4, {Al(NiPrH)3}3, 5, Al2(NEt2)2(NiPr2)2H2, 6, and AlCl3(NiPrH2)2{Al(NH3)(NH2)[Al(NiPrH)(NiPr)Cl]2}2, 7, were synthesized by substitution reactions and characterized by mass spectra, IR… CONTINUE READING