Study of the water/poly(ethylene glycol) interface by IR-visible sum-frequency generation spectroscopy
@article{Dreesen2001StudyOT, title={Study of the water/poly(ethylene glycol) interface by IR-visible sum-frequency generation spectroscopy}, author={L. Dreesen and C. Humbert and P. Hollander and A. A. Mani and K. Ataka and P. Thiry and A. Peremans}, journal={Chemical Physics Letters}, year={2001}, volume={333}, pages={327-331} }
We used infrared-visible sum-frequency generation spectroscopy to investigate the vibrational properties of the water/poly(ethylene glycol) interface in the 2800–3800 cm−1 spectral range. The vibrational fingerprint of the interface differs significantly from the one associated with the air/poly(ethylene glycol) interface. It is shown that the poly(ethylene glycol) molecular arrangement, originally relatively well-ordered, becomes disorganised in the presence of water. Moreover, a new OH band… CONTINUE READING
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