Study of the coordination and solution structures for the interaction systems between diperoxidovanadate complexes and 4-(pyridin-2-yl)pyrimidine-like ligands.

Abstract

To understand the substitution effects of 4-(pyridin-2-yl)pyrimidine (pprd) on the coordination reaction equilibria, the interactions between a series of the pprd-like ligands and [OV(O(2))(2)(H(2)O)](-) or [OV(O(2))(2)(HOD)](-) or [OV(O(2))(2)(D(2)O)](-) (bpV) have been explored by a combination of multinuclear ((1)H, (13)C, and (51)V) magnetic resonance… (More)
DOI: 10.1039/c2dt12334g

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