Studies on the Synthesis of Sesquiterpene Lactones, 16. The Syntheses of 11β,13-Dihydrokauniolide, Estafiatin, Isodehydrocostuslactone, 2-Oxodesoxyligustrin, Arborescin, 1,10-Epiarborescin, 11β,13-Dihydroludartin, 8-Deoxy-11β,13-dihydrorupicolin B, 8-Deoxyrupicolin B, 3,4-Epiludartin, Ludartin, Kaun

M. Ando; K. Ibayashi; N. Minami; T. Nakamura; K. Isogai; H. Yoshimura

DOI:10.1021/NP50106A001

Corpus ID: 84420139

Studies on the Synthesis of Sesquiterpene Lactones, 16. The Syntheses of 11β,13-Dihydrokauniolide, Estafiatin, Isodehydrocostuslactone, 2-Oxodesoxyligustrin, Arborescin, 1,10-Epiarborescin, 11β,13-Dihydroludartin, 8-Deoxy-11β,13-dihydrorupicolin B, 8-Deoxyrupicolin B, 3,4-Epiludartin, Ludartin, Kaun

@article{Ando1994StudiesOT,
  title={Studies on the Synthesis of Sesquiterpene Lactones, 16. The Syntheses of 11β,13-Dihydrokauniolide, Estafiatin, Isodehydrocostuslactone, 2-Oxodesoxyligustrin, Arborescin, 1,10-Epiarborescin, 11β,13-Dihydroludartin, 8-Deoxy-11β,13-dihydrorupicolin B, 8-Deoxyrupicolin B, 3,4-Epiludartin, Ludartin, Kaun},
  author={M. Ando and K. Ibayashi and N. Minami and T. Nakamura and K. Isogai and H. Yoshimura},
  journal={Journal of Natural Products},
  year={1994},
  volume={57},
  pages={433-445}
}

M. Ando, K. Ibayashi, +3 authors H. Yoshimura

Published 1994

Chemistry

Journal of Natural Products

A total of eleven naturally occurring guaianolides, 11β,13-dihydrokau- niolide, estafiatin, isodehydrocostuslactone, 2-oxodesoxyligustrin, arborescen, 11β,13-dihydroludartin, 8-deoxy-11b,13-dihydrorupicolin B, ludartin, kauniolide, dehydroleucodin, and leucodin, and three related compounds, 1,10-epiarborescin, 8-deoxyrupicolin B, and 3,4-epiludartin, were synthesized through a common cationic intermediate A, which was derived from (11S)-1β-(mesyloxy)eudesm-3-eno-12,6α-lactone [2] by solvolytic… CONTINUE READING

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