Studies on bismuth carboxylates—synthesis and characterization of a new structural form of bismuth(III) dipicolinate

@article{Anjaneyulu2011StudiesOB,
  title={Studies on bismuth carboxylates—synthesis and characterization of a new structural form of bismuth(III) dipicolinate},
  author={O. Anjaneyulu and K C Kumara Swamy},
  journal={Journal of Chemical Sciences},
  year={2011},
  volume={123},
  pages={131-137}
}
AbstractSynthesis and X-ray structure of a new bismuth dipicolinate cooordination polymer, {[Bi((2,6-O2C)2C5H3N)((2-HO2C-6-O2C)C5H3N)(H2O)]2.5H2O}n (7) are presented. Compound 7 has dimeric units with a Bi2O2 skeleton that are linked by additional weak Bi–O interactions leading to a polymeric structure. The overall coordination number at bismuth is 9 [two Bi–N and seven Bi–O bonds]. New routes to a second crystalline modification (4′) of the previously reported coordination polymer, bismuth… CONTINUE READING