Structure and function of type I copper in multicopper oxidases

@article{Sakurai2007StructureAF,
  title={Structure and function of type I copper in multicopper oxidases},
  author={Takeshi Sakurai and Kunishige Kataoka},
  journal={Cellular and Molecular Life Sciences},
  year={2007},
  volume={64},
  pages={2642-2656}
}
The type I copper center in multicopper oxidases is constructed from 1Cys2His and weakly coordinating 1Met or the non-coordinating 1Phe/1Leu, and it exhibits spectral properties and an alkaline transition similar to those of the blue copper center in blue copper proteins. Since the type I copper center in multicopper oxidases is deeply buried inside the protein molecule, electron transfers to and from type I copper are performed through specific pathways: the hydrogen bond between an amino acid… CONTINUE READING

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