Structure and criticality of ionic fluids

@article{Schrer2004StructureAC,
  title={Structure and criticality of ionic fluids},
  author={W. Schr{\"o}er and H. Weing{\"a}rtner},
  journal={Pure and Applied Chemistry},
  year={2004},
  volume={76},
  pages={19 - 27}
}
Two properties render electrolyte theories difficult, namely the long-range nature of the Coulomb interactions and the high figures of the Coulomb energy at small ion separations. In solvents of low dielectric constant, where the Coulomb interactions are particularly strong, electrical conductance and dielectric spectra suggest that the ion distribution involves dipolar ion pairs, which then interact with the free ions and with other dipolar pairs. The dipole-dipole interactions between ion… Expand
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  • W. SCHRÖER AND H. WEINGÄRTNER © 2004 IUPAC, Pure and Applied Chemistry
  • 2004
Theory of dielectrics