Structural diversity and magnetic properties in 1D and 2D azido-bridged cobalt(II) complexes with 1,2-bis(2-pyridyl)ethylene.

@article{Boonmak2011StructuralDA,
  title={Structural diversity and magnetic properties in 1D and 2D azido-bridged cobalt(II) complexes with 1,2-bis(2-pyridyl)ethylene.},
  author={Jaursup Boonmak and Motohiro Nakano and Sujittra Youngme},
  journal={Dalton transactions},
  year={2011},
  volume={40 6},
  pages={1254-60}
}
By utilizing a flexible co-ligand 1,2-bis(2-pyridyl)ethylene (2,2'-bpe), two new azido-bridged cobalt(II) complexes with the formulae [Co₃(N₃)₆(OH₂)₂(2,2'-bpe)₂](n)(2,2'-bpe)(n) (1) and [Co(N₃)₂(2,2'-bpe)₂](n) (2) have been synthesized and structurally characterized. Compound 1 shows an uncommon 1D chain comprised of double EO azido bridged five- and six… CONTINUE READING