Structural characterization of silver dialkylphosphite salts using solid-state 109Ag and 31P NMR spectroscopy, IR spectroscopy and DFT calculations.

@article{Chen2010StructuralCO,
  title={Structural characterization of silver dialkylphosphite salts using solid-state 109Ag and 31P NMR spectroscopy, IR spectroscopy and DFT calculations.},
  author={Fu Ren Chen and Roderick E Wasylishen},
  journal={Magnetic resonance in chemistry : MRC},
  year={2010},
  volume={48 4},
  pages={270-5}
}
High-resolution solid-state (109)Ag and (31)P NMR spectroscopy was used to investigate a series of silver dialkylphosphite salts, Ag(O)P(OR)(2) (R = CH(3), C(2)H(5), C(4)H(9) and C(8)H(17)), and determine whether they adopt keto, enol or dimer structures in the solid state. The silver chemical shift, CS, tensors and |J((109)Ag, (31)P)| values for these… CONTINUE READING