Structural characterization of Pu[N(SiMe(3))(2)](3), a synthetically useful nonaqueous plutonium(III) precursor.

Abstract

A rare, and synthetically versatile, nonaqueous plutonium complex, Pu[N(SiMe3)2]3 (1), has been structurally characterized by single-crystal X-ray diffraction for the first time and reveals significantly shorter agostic interactions compared to the cerium(III) analogue, indicating possible covalency differences. 

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