Structural and oxo-transfer reactivity differences of hexacoordinate and pentacoordinate (nitro)(tetraphenylporphinato)cobalt(III) derivatives.

Abstract

The oxo-transfer catalyst (nitro)(pyridyl)cobalt(III) tetraphenylporphyrin has been reinvestigated by substitution of the distal pyridine ligand with 4-N,N-dimethylaminopyridine and 3,5-dichloropyridine. Differences in their structures and in the reactivity of the compounds toward catalytic secondary oxo transfer were investigated by FT-IR and UV-visible… (More)

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Cite this paper

@article{Goodwin2001StructuralAO, title={Structural and oxo-transfer reactivity differences of hexacoordinate and pentacoordinate (nitro)(tetraphenylporphinato)cobalt(III) derivatives.}, author={Jacob Goodwin and Robert C Bailey and Winifred Pennington and Ron D Rasberry and T. Green and S Shasho and M Yongsavanh and Virginia Echevarria and Jessica A. Tiedeken and C. Brown and Gwendolyn Fromm and Susan Lyerly and N. Watson and A. Long and N De Nitto}, journal={Inorganic chemistry}, year={2001}, volume={40 17}, pages={4217-25} }