Structural and cytotoxic study of new Pt(II) and Pd(II) complexes with the bi-heterocyclic ligand mepirizole.

@article{Onoa1999StructuralAC,
  title={Structural and cytotoxic study of new Pt(II) and Pd(II) complexes with the bi-heterocyclic ligand mepirizole.},
  author={Gloria Bibiana Onoa and V. L{\'o}pez-Arza Moreno and Merc{\`e} Font-Bard{\'i}a and Xavier Cavero Solans and Jose Manuel Perez and Carlos Alonso},
  journal={Journal of inorganic biochemistry},
  year={1999},
  volume={75 3},
  pages={
          205-12
        }
}
Pd(II) and Pt(II) complexes of formulae [MLCl2], where L = mepirizole, were synthesized and characterized. Two complexes were obtained and studied by different techniques: IR, 1H and 13C NMR and XPS spectroscopies and mass spectrometry (electrospray). The crystal structure of the complex cis-dichloro-4-methoxy-2-(5-methoxy-3-methyl- pyrazol-1-yl)-6-methyl-pyrimidinepalladium(II), [Pd(mep)Cl2], was studied by crystal X-ray diffraction. It consists of discrete molecules with planar geometry. Pd… CONTINUE READING
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