Structural Analysis of Bisphenol-A and its Methylene, Sulfur, and Oxygen Bridged Bisphenol Analogs

  title={Structural Analysis of Bisphenol-A and its Methylene, Sulfur, and Oxygen Bridged Bisphenol Analogs},
  author={Caitlin Lim and Joseph M. Tanski},
  journal={Journal of Chemical Crystallography},
  • Caitlin LimJ. Tanski
  • Published 27 June 2007
  • Chemistry, Materials Science
  • Journal of Chemical Crystallography
The molecular structures of bisphenol-A, C(CH3)2(p-C6H4OH)2 (monoclinic, P21/n, a = 11.1940(6) Å, b = 18.738(1) Å, c = 17.8623(9) Å, β = 100.571(1)°), its methylene (CH2) and heteroatom (S, O) bridged analogs, CH2(p-C6H4OH)2 (monoclinic, P21/n, a = 5.4351(1) Å, b = 20.7895(3) Å, c = 8.8432(1) Å, β = 93.419(1)°), S(p-C6H4OH)2 (monoclinic, P21/n, a = 5.5115(1) Å, b = 21.0666(2) Å, c = 8.6917(1) Å, β = 92.962(1)°) and O(p-C6H4OH)2 (orthorhombic, Pbcn, a = 5.2745(5) Å, b = 8.2724(8) Å, c = 22.085(2… 

The crystal structure of 1,2-bis(4-pyridyl)ethane - 4,4-dihydroxydiphenylmethane (1/1), C25H21N2O2

  • Jie ChengJue Chen
  • Chemistry
    Zeitschrift für Kristallographie - New Crystal Structures
  • 2021
Abstract C25H21N2O2, monoclinic, C2/c (no. 15), a = 11.041(2) Å, b = 7.859(2) Å, c = 24.131(5) Å, β = 95.26(3)°, V = 2085.1(7) Å3, Z = 4, R gt (F) = 0.0486, wR ref (F 2) = 0.1402, T = 295 K.

3,3′-Dinitrobisphenol A

The title compound [systematic name: 2,2′-dinitro-4,4′-(propane-2,2-diyl)diphenol], C15H14N2O6, crystallizes with two molecules in the asymmetric unit. Both have a trans conformation for their OH

Synthesis and crystal structures of 5,5′-(propane-2,2-diyl)bis(2-hydroxybenzaldehyde) and 5,5′-(propane-2,2-diyl)bis(2-hydroxyisophthalaldehyde)

The molecule of (1) presents a >C(CH3)2 group that bridges two nearly planar salicylaldehyde groups, each comprising a planar phenyl ring bonded with a hydroxyl and an aldehyde group. Similarly,


  • E. HefterJ. Tanski
  • Chemistry
    Acta crystallographica. Section E, Structure reports online
  • 2011
In the title compound, C12H10BrN, the dihedral angle between the benzene rings is 52.5 (1)°, whereas the pitch angles, or the angles between the mean plane of each aryl group ‘propeller blade’ and

Synthesis and Characterization of Bio-based Epoxy Resins Derived from Vanillyl Alcohol

Vanillyl alcohol, a lignin derived aromatic diol, is a potential platform chemical for the production of renewable epoxy thermosets. A bio-based bisphenolic analogue, bisguaiacol (BG), was



Covalent titanium aryldioxy one-, two-, and three-dimensional networks and their examination as Ziegler-Natta catalysts.

CMON were assayed for ethylene and propylene polymerization activity via the addition of methylaluminoxane, mediocre Ziegler-Natta catalysts that generate polydisperse, linear polyethylene and atactic polypropylene.

Crystal Engineering Using Bisphenols. Chains, Ladders and Sheets Formed by the Adducts of 1,4‐Diazabicyclo[2.2.2]octane with Bisphenols: Structures of Adducts with 4,4'‐Isopropylidenediphenol (1/1), 4,4'‐Oxodiphenol (1/1) and 4,4'‐Thiodiphenol (1/1 and 2/1)

4,4'-Isopropylidenediphenol-1,4-diazabicyclo[2.2.2]octane (1/1), (1), C 15 H 16 O 2 .C 6 H 12 N 2 , monoclinic, P2/a, a = 11.385(2), b = 6.5565(12), c = 13.076(2)A, β = 96.240(11)°, with Z = 2; the

Crystal Engineering Using Bisphenols and Trisphenols. Complexes with Hexamethylenetetramine (HMTA): Strings, Multiple Helices and Chains-of-Rings in the Crystal Structures of the Adducts of HTMA with 4,4'-Thiodiphenol (1/1), 4,4'-Sulfonyldiphenol (1/1), 4,4'-Isopropylidenediphenol (1/1), 1,1,1-Tris(

The 4,4'-bisphenols (1), X(C 6 H 4 OH) 2 [a, X = nil; b, X= O; c, X = S; d, X = SO 2 ; e, X = CO ; f, X = CH 2 ; g, X = CMe2; h, X = C(CF 3 ) 2 ], when co-crystallized from alcoholic solutions with

Covalent metal-organic networks: pyridines induce 2-dimensional oligomerization of (mu-OC6H4O)2Mpy2 (M = Ti, V, Zr).

Through protolytic quenching studies and by correspondence of powder XRD patterns with known titanium species, the remaining complexes were structurally assigned and single-crystal X-ray diffraction experiments confirmed the pleated sheet structure of 2-Ti, the flatsheet structure of 3- Ti, and the rippled sheet structures of 4-Ti.

Crystal engineering using bisphenols and trisphenols. Complexes with 1,10-phenanthroline: hydrogen-bonded chains in adducts with 4,4'-biphenol (1/1) and 4,4'-sulfonyldiphenol (2/3), pi-pi stacked chains in the (1/2) adduct with 4,4'-thiodiphenol, and pairwise-interwoven nets in 1,1,1-tris(4-hydroxyp

In 4,4'-biphenol-1,10-phenanthroline (1/1) the diphenol molecules lie across centres of inversion and the phenanthro line molecules lies across twofold rotation axes; the phenAnthroline molecules act as chain-building units and the molecular components are linked into steeply zigzag C(16) chains parallel to [101] by means of O-H.N hydrogen bonds.

Measurement of estrogenic activity of chemicals for the development of new dental polymers.

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