Structural, spectroscopic, and multiconfigurational quantum chemical investigations of the electron-rich metal-metal triple-bonded Tc(2)X(4)(PMe(3))(4) (X = Cl, Br) complexes.

Abstract

The compounds Tc(2)Cl(4)(PMe(3))(4) and Tc(2)Br(4)(PMe(3))(4) were formed from the reaction between (n-Bu(4)N)(2)Tc(2)X(8) (X = Cl, Br) and trimethylphosphine. The Tc(II) dinuclear species were characterized by single-crystal XRD, UV-visible spectroscopy, and cyclic voltammetry techniques, and the results are compared to those obtained from density… (More)
DOI: 10.1021/ic100641j

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Cite this paper

@article{Poineau2010StructuralSA, title={Structural, spectroscopic, and multiconfigurational quantum chemical investigations of the electron-rich metal-metal triple-bonded Tc(2)X(4)(PMe(3))(4) (X = Cl, Br) complexes.}, author={Fr{\'e}d{\'e}ric Poineau and Paul M Forster and Tanya K Todorova and Laura Gagliardi and Alfred P. Sattelberger and Kenneth R. Czerwinski}, journal={Inorganic chemistry}, year={2010}, volume={49 14}, pages={6646-54} }