Structural, electronic, and magnetic properties of UFeS3 and UFeSe3.

  title={Structural, electronic, and magnetic properties of UFeS3 and UFeSe3.},
  author={G. Jin and E. Ringe and G. Long and F. Grandjean and M. Sougrati and E. Choi and Daniel M. Wells and M. Balasubramanian and J. Ibers},
  journal={Inorganic chemistry},
  volume={49 22},
Black prisms of UFeS(3) and UFeSe(3) have been synthesized by solid-state reactions of U, Fe, and S or Se with CsCl as a flux at 1173 K. The structure of these isostructural compounds consists of layers of edge- and corner-sharing FeS(6) or FeSe(6) octahedra that are separated by layers of face- and edge-sharing US(8) or USe(8) bicapped trigonal prisms. The isomer shifts in the iron-57 Mössbauer spectra of both UFeS(3) and UFeSe(3) are consistent with the presence of high-spin iron(II) ions… Expand
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