Strong Metal-Support Interactions between Gold Nanoparticles and Nonoxides.

@article{Tang2016StrongMI,
  title={Strong Metal-Support Interactions between Gold Nanoparticles and Nonoxides.},
  author={Hailian Tang and Jiake Wei and Fei Liu and Botao Qiao and Xiaoli Pan and Carilyn Torruellas and Jingyue Jimmy Liu and Junhu Wang and Tao Zhang},
  journal={Journal of the American Chemical Society},
  year={2016},
  volume={138 1},
  pages={56-9}
}
The strong metal-support interaction (SMSI) is of great importance for supported catalysts in heterogeneous catalysis. We report the first example of SMSI between Au nanoparticles (NPs) and hydroxyapatite (HAP), a nonoxide. The reversible encapsulation of Au NPs by HAP support, electron transfer, and changes in CO adsorption are identical to the classic SMSI except that the SMSI of Au/HAP occurred under oxidative condition; the opposite condition for the classical SMSI. The SMSI of Au/HAP not… CONTINUE READING
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