Stretch Out or Fold Back? Conformations of Dinuclear Gold(I) N-Heterocyclic Carbene Macrocycles.


We report the synthesis and characterization of 12 new dinuclear gold(I) N-heterocyclic carbene (NHC) complexes and the corresponding imidazolium precursors. The focus lies in a systematic study of conformational changes and intra- and intermolecular gold-gold and π-π interactions of dinuclear gold(I) carbene complexes. Common to all members of the series… (More)
DOI: 10.1021/ic502751s


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