Stereoselective anti aldol reactions of erythrulose derivatives. Functionalized chiral d3 and d4 synthons.

Abstract

An improved procedure for the synthesis of anti aldols from protected erythrulose derivatives is reported. The preparation of functionalized d3 and d4 synthons with various stereochemical arrays by means of this methodology is described and subsequently applied to a stereoselective formal synthesis of the natural metabolite goniothalesdiol. 

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Cite this paper

@article{Murga2004StereoselectiveAA, title={Stereoselective anti aldol reactions of erythrulose derivatives. Functionalized chiral d3 and d4 synthons.}, author={Juan Murga and Purificaci{\'o}n Ruiz and Eva Falomir and Miguel Card{\'a} and Gabriel Peris and Juan Alberto Marco}, journal={The Journal of organic chemistry}, year={2004}, volume={69 6}, pages={1987-92} }