Stepwise engineering of pore environments and enhancement of CO2/R22 adsorption capacity through dynamic spacer installation and functionality modification.

@article{Chen2017StepwiseEO,
  title={Stepwise engineering of pore environments and enhancement of CO2/R22 adsorption capacity through dynamic spacer installation and functionality modification.},
  author={Cheng-Xia Chen and Qian-Feng Qiu and Chen-Chen Cao and M. Y. Pan and Hai-Ping Wang and Jijun Jiang and Zhang-Wen Wei and Kelong Zhu and Guangqin Li and Cheng-Yong Su},
  journal={Chemical communications},
  year={2017},
  volume={53 83},
  pages={11403-11406}
}
Through stepwise post-synthetic spacer insertion and click reactions, six Zr-MOFs with different types and amounts of functional groups have been constructed based on proto-MOF PCN-700. Their gas adsorption capacities and selectivities have been greatly improved and finely tuned, demonstrating the combinatorial effect of pore surface modification and pore space partition. 
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