Steady-state and laser photolysis studies of substituted 2H-azirines: spectroscopy, absolute rates, and arrhenius behavior for the reaction of nitrile ylides with electron deficient olefins

@inproceedings{Padwa1984SteadystateAL,
  title={Steady-state and laser photolysis studies of substituted 2H-azirines: spectroscopy, absolute rates, and arrhenius behavior for the reaction of nitrile ylides with electron deficient olefins},
  author={Albert Padwa and Robert J. Rosenthal and William Dent and Pedro Ferreira Moreira Filho and Nicholas J. Turro and David A. Hrovat and Ian R. Gould},
  year={1984}
}
Par irradiation UV des azirines substituees a 298 K, decyclisation en nitrile ylures qui peuvent etre captees par l'acrylate de methyle ou le methanol. En absence d'intercepteur, l'ylure donne une electrocyclisation en −1,5 suivie d'un deplacement de H sigmatrope-1,3 conduisant a un derive de l'isoindole. Spectres UV