Statistical thermodynamics of solutions

@article{Prigogine1956StatisticalTO,
  title={Statistical thermodynamics of solutions},
  author={I. Prigogine and A. Bellemans and A. Englert-Chwoles},
  journal={Journal of Chemical Physics},
  year={1956},
  volume={24},
  pages={518-527}
}
  • I. Prigogine, A. Bellemans, A. Englert-Chwoles
  • Published 1956
  • Chemistry
  • Journal of Chemical Physics
    • A new approach to the statistical problem of solutions is presented, which combines the main ideas of the cell method and of the theorem of corresponding states. The basic assumption is that the cell partition function of a molecule in the solution may be formally expressed by the same function as in pure liquid, but with other well‐defined values of the reduced temperature and volume.For pure liquids this theory reduces to the usual theorem of corresponding states. The excess properties of the… CONTINUE READING
    View via Publisher
    64 Citations
    Background Citations
    2
    64 Citations
    Citation Type

    Citation Type

    The second-order theory of conformal solutions
    • W. B. Brown
    • Mathematics
    • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
    • 1957
    • 27
    Theory of Multi‐Component Fluid Mixtures. II. A Corresponding States Treatment
    • 28
    Small Perturbations in Solution Theory
    • 31
    Chapter VII Thermodynamic Properties of Fluid Mixtures
    MOLECULAR PRINCIPLE OF CORRESPONDING STATES FOR VISCOSITY AND THERMAL CONDUCTIVITY OF FLUID MIXTURES
    • 9
    Consideration of some dilute-solution phenomena based on an expression for the Gibbs free energy
    • 8
    Theory of Multi‐Component Fluid Mixtures. I. Statistical Order‐Disorder Analysis in Multi‐Component Fluid Mixtures
    • 17
    Statistical Mechanics of Multicomponent Systems: Perturbation Theory
    • 6
    Excess Volumes in Binary Liquid Mixtures of Simple Molecules
    • 9
    Perturbation theory and one-fluid corresponding states theories for fluid mixtures
    • 27

    References

    SHOWING 1-10 OF 16 REFERENCES
    Application of the Cell Method to the Statistical Thermodynamics of Solutions
    • 84
    The statistical thermodynamics of multicomponent systems
    • H. Longuet-higgins
    • Chemistry
    • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
    • 1951
    • 233
    Sur la thermodynamique statistique des solutions binaires
    • 43
    Thermodynamics of ordering alloys, II. The gold-copper system
    • 45
    Application of the cell method to the statistical thermodynamics of solutions. II. Experimental
    • 41
    Applications of the Free Volume Theory of Binary Mixtures
    • 28
    Molecular Theory Of Gases And Liquids
    • 12,064
    • PDF
    On the Entropy of Mixing of Liquid Solutions
    • 11
    Thermodynamic Properties of the System Methane-Carbon Monoxide at 90.67°K
    • 7
    Virial Coefficients of Benzene‐Cyclohexane Mixtures, and Theories of Liquid Solutions
    • 13