Statistical thermodynamics of solutions

  title={Statistical thermodynamics of solutions},
  author={I. Prigogine and A. Bellemans and A. Englert-Chwoles},
  journal={Journal of Chemical Physics},
  • I. Prigogine, A. Bellemans, A. Englert-Chwoles
  • Published 1956
  • Chemistry
  • Journal of Chemical Physics
  • A new approach to the statistical problem of solutions is presented, which combines the main ideas of the cell method and of the theorem of corresponding states. The basic assumption is that the cell partition function of a molecule in the solution may be formally expressed by the same function as in pure liquid, but with other well‐defined values of the reduced temperature and volume.For pure liquids this theory reduces to the usual theorem of corresponding states. The excess properties of the… CONTINUE READING
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