Standards for photoluminescence quantum yield measurements in solution (IUPAC Technical Report)

@article{Brouwer2011StandardsFP,
  title={Standards for photoluminescence quantum yield measurements in solution (IUPAC Technical Report)},
  author={Albert M. Brouwer},
  journal={Pure and Applied Chemistry},
  year={2011},
  volume={83},
  pages={2213 - 2228}
}
  • A. M. Brouwer
  • Published 2011
  • Chemistry, Engineering
  • Pure and Applied Chemistry
The use of standards for the measurement of photoluminescence quantum yields (QYs) in dilute solutions is reviewed. Only three standards can be considered well established. Another group of six standards has been investigated by several independent researchers. A large group of standards is frequently used in recent literature, but the validity of these is less certain. The needs for future development comprise: (i) confirmation of the validity of the QY values of many commonly used standard… Expand

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References

SHOWING 1-10 OF 20 REFERENCES
Comparison of methods and achievable uncertainties for the relative and absolute measurement of photoluminescence quantum yields.
TLDR
This work compares two relative and one absolute fluorometric method for the determination of the fluorescence quantum yields of quinine sulfate dihydrate, coumarin 153, fluorescein, rhodamine 6G, and rhodamines 101, thereby providing evaluated standard operation procedures for Φ(f) measurements and, simultaneously, a set of assessed Φ (f) standards. Expand
Method of Determination of Emission Properties of Very Weakly Emitting Species Ensuring Elimination of Emission of Impurities
TLDR
A new type of spectrofluorimeter, composed of a high-performance liquid chromatography system directly connected to a fluorescence detector and an absorption photodiode array detector, designed for studying the emission of weakly emitting species. Expand
Handbook of photochemistry
. Photophysics of Organic Molecules in Solution Triplet-State Energies: Ordered Flash Photolysis: Designing Experiments Low Temperature Photophysics of Organic Molecules Ground-State AbsorptionExpand
Principles of fluorescence spectroscopy
Fluorescence methods are being used increasingly in biochemical, medical, and chemical research. This is because of the inherent sensitivity of this technique. and the favorable time scale of theExpand
Effectiveness of Purge-and-Trap for Measurement of Volatile Organic Compounds in Aged Soils.
TLDR
Compared with three methods for determination of VOCs in aged field samples, hot solvent extraction proved to be much more effective than the U.S. EPA-approved purge-and-trap technique, indicating the inefficiency of purge- and-trap as a method for evaluating vapor extraction remediation technology. Expand
Fluorescence Efficiency of Laser Dyes*
  • K. Drexhage
  • Materials Science, Chemistry
  • Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry
  • 1976
The fluorescence efficiency of xanthene dyes, oxazine dyes, and 7-aminocoumarins is discussed. Relations with the molecular structure are pointed out and dependence on solvent and temperature isExpand
"J."
however (for it was the literal soul of the life of the Redeemer, John xv. io), is the peculiar token of fellowship with the Redeemer. That love to God (what is meant here is not God’s love to men)Expand
Standard Reference Materials: A Fluorescence Standard Reference Material: Quinine Sulfate Dihydrate, National Bureau of Standards Special Publication 260-64
  • National Bureau of Standards,
  • 1980
Drexhage
  • J . Lumin .
  • 1991
...
1
2
...