Stabilizing and Activating Nitrogen Catenates.


The remarkably stable catenated hexa-nitrogen chain in bis(benzotriazene-4-one) is structurally, theoretically, and spectroscopically characterized to illustrate the durability of the central N-N bond in this hexaazo chain. The reactions of this species illustrate the potential of these nitrogen catenates for the preparation of other condensed heterocycles… (More)
DOI: 10.1002/chem.201501241


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