Sr8MgB18O36: a new alkaline-earth borate with a novel zero-dimensional (B18O36)18- anion ring.


A new polyborate, Sr8MgB18O36, has been synthesized. Its crystal structure was determined from single-crystal X-ray diffraction data, and characterizations were made by differential scanning calorimetry, Fourier transform IR, UV-vis-near-IR diffuse-reflectance, and first-principles calculations. The structure of Sr8MgB18O36 contains a novel isolated anionic… (More)
DOI: 10.1021/ic401167z


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