We investigate the Hawking radiation in the gauge-Higgs-Yukawa theory. The ballistic model is proposed as an effective description of the system. We find that a spherical domain wall around the black hole is formed by field dynamics rather than thermal phase-transition. The formation is a general property of the black hole whose Hawking temperature is equal to or greater than the energy scale of the theory. The formation of the electroweak wall and that of the GUT wall are shown. We also find a phenomenon of the spontaneous charging-up of the black hole by the wall. The Hawking radiation drives a mechanism of the charge-transportation into the black hole when Cand CP-violation are assumed. The mechanism can strongly transport the hyper-charge into a black hole of the electroweak scale.