Spectroscopic identification and stability of the intermediate in the OH + HONO2 reaction.


The reaction of nitric acid with the hydroxyl radical influences the residence time of HONO(2) in the lower atmosphere. Prior studies [Brown SS, Burkholder JB, Talukdar RK, Ravishankara AR (2001) J Phys Chem A 105:1605-1614] have revealed unusual kinetic behavior for this reaction, including a negative temperature dependence, a complex pressure dependence… (More)
DOI: 10.1073/pnas.0800320105


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