Spectroscopic and theoretical investigations of vibrational frequencies in binary unsaturated transition-metal carbonyl cations, neutrals, and anions.

@article{Zhou2001SpectroscopicAT,
  title={Spectroscopic and theoretical investigations of vibrational frequencies in binary unsaturated transition-metal carbonyl cations, neutrals, and anions.},
  author={Mingfei Zhou and Lester Andrews and Charles W. Jr. Bauschlicher},
  journal={Chemical reviews},
  year={2001},
  volume={101 7},
  pages={
          1931-61
        }
}
Figure 18 presents the C-O stretching vibrational frequencies of the first-row transition-metal monocarbonyl cations, neutrals, and anions in solid neon; similar diagrams have been reported for neutral MCO species in solid argon, but three of the early assignments have been changed by recent work and one new assignment added. The laser-ablation method produces mostly neutral atoms with a few percent cations and electrons for capture to make anions; in contrast, thermal evaporation gives only… CONTINUE READING
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