Spectroscopic and QM/MM investigations of Chloroperoxidase catalyzed degradation of orange G.

Abstract

Chloroperoxidase (CPO), a heme-thiolate protein, from Caldariomyces fumago catalyzes a plethora of reactions including halogenation, dismutation, epoxidation, and oxidation. Although all CPO-catalyzed reactions go through a common intermediate, compound I, different mechanisms are followed in subsequent transformations. To understand the mechanism of CPO… (More)
DOI: 10.1016/j.abb.2016.02.026

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