Spectroelectrochemical Investigation of the One-Electron Reduction of Nonplanar Nickel(II) Porphyrins.


The electrochemical reduction of a series of nickel porphyrins with an increasing number of substituents was investigated in acetonitrile. A one-electron reduction of [5,15-bis(1-ethylpropyl)porphyrinato]nickel(II) leads to π-anion radicals and to efficient formation of phlorin anions, presumably by disproportionation and subsequent protonation of the… (More)
DOI: 10.1002/cphc.201600698


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