Specific solvation of benzyl methacrylate in 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ionic liquid.

@article{Matsugami2013SpecificSO,
  title={Specific solvation of benzyl methacrylate in 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ionic liquid.},
  author={Masaru Matsugami and K. Fujii and T. Ueki and Yuzo Kitazawa and Y. Umebayashi and Masayoshi Watanabe and M. Shibayama},
  journal={Analytical sciences : the international journal of the Japan Society for Analytical Chemistry},
  year={2013},
  volume={29 3},
  pages={
          311-4
        }
}
It has been established that poly(benzyl methacrylate) in a room-temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([C2mIm(+)][TFSA(-)]), exhibits lower critical solution temperature (LCST)-type phase separation. In this work we investigated the solvation structure of benzyl methacrylate monomer in the ionic liquid by using high-energy X-ray diffraction with the aid of a molecular dynamics simulation. It was found that the C2mIm cation orderly distributes… Expand
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