Source of oxygen in the conversion of 2-tridecanone to undecyl acetate by Pseudomonas cepacia and Nocardia sp.

@article{Britton1974SourceOO,
  title={Source of oxygen in the conversion of 2-tridecanone to undecyl acetate by Pseudomonas cepacia and Nocardia sp.},
  author={L. Britton and J. Brand and A. J. Markovetz},
  journal={Biochimica et biophysica acta},
  year={1974},
  volume={369 1},
  pages={
          45-9
        }
}
Abstract Cell-free extracts from Pseudomonas cepacia and Nocardia sp. when supplied with NADPH accumulated undecyl acetate from 2-tridecanone in the presence of an esterase inhibitor, tetraethyl pyrophosphate. Mass spectra of undecyl acetate formed in an 16O2-atmosphere exhibited characteristic oxygencontaining ions of m/e 61, 73, and 116. In experiments with 18O2, these ions appeared at m/e 63, 75, and 118. Absence of a significant peak at m/e 45 in the 18O-containing ester established that… Expand
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A pathway for utilization of 2-tridecanone was proposed that is consistent with, but not confirmed by, the data presented, and it is established that some unique mechanism that involves subterminal oxidation must exist to degrade 2-Tride canone. Expand
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TLDR
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