Some reactions of trifluoropyruvic ester with nucleophilic reagents

@inproceedings{Knunyants1967SomeRO,
  title={Some reactions of trifluoropyruvic ester with nucleophilic reagents},
  author={I. L. Knunyants and Natalia Gambaryan and V. V. Tyuleneva},
  year={1967}
}
1. It was shown that the ketonic carbonyl group in the methyl ester of trifluoropyruvic acid is highly electrophilic. 2. Reaction with methanol gave the corresponding polyketal, while reaction with ketene. cyclohexyl isocyanide or triethyl phosphite gave cyclic adducts. 3. In the adducts, containing 2 moles of the trifluoropyruvic ester per mole of ketene or cyclohexyl isocyanide, the two moieties of the fluorinated keto ester are connected via the formation of a C-O… CONTINUE READING

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