Some aspects of multicomponent excess free energy models with subregular binaries

@inproceedings{Cheng1994SomeAO,
  title={Some aspects of multicomponent excess free energy models with subregular binaries},
  author={Weiji Cheng and Jibamitra Ganguly},
  year={1994}
}
Abstract We have shown that two of the most commonly used multicomponent formulations of excess Gibbs free energy of mixing, those by Wohl (1946, 1953) and Redlich and Kister (1948), are formally equivalent if the binaries are constrained to have subregular properties, and also that other subregular multicomponent formulations developed in the mineralogical and geochemical literature are equivalent to, or higher order extensions of, these formulations. We have also presented a compact… CONTINUE READING