Solution Synthesis of Semiconducting Two-Dimensional Polymer via Trimerization of Carbonitrile.

Abstract

The synthesis of crystalline two-dimensional polymers (2DPs) with proper bandgaps and well-defined repeating units presents a great challenge to synthetic chemists. Here we report the first solution synthesis of a single-layer/few-layer triazine-based 2DP via trimerization of carbonitrile at the interface of dichloromethane and trifluoromethanesulfonic acid… (More)
DOI: 10.1021/jacs.7b05025

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