Solubility of Organophosphorus Metal Extractants in Supercritical Carbon Dioxide

@inproceedings{Meguro1998SolubilityOO,
  title={Solubility of Organophosphorus Metal Extractants in Supercritical Carbon Dioxide},
  author={Yoshihiro Meguro and Shuichi Iso and and Takayuki Sasaki and Zenko Yoshida},
  year={1998}
}
The solubility (S) of several liquid organophosphorus compounds, tributyl phosphate (TBP), diisodecylphosphoric acid (DIDPA), di-(2-ethylhexyl)phosphoric acid (DEHPA), dihexyl-(N,N-diethylcarbamoyl)methylphosphonate (CMP), and octyl(phenyl)(N,N-diisobutylcarbamoyl)methylphosphine oxide (CMPO), in supercritical CO2 was determined over temperature and pressure ranges of 30−90 °C and 7.5−25 MPa. The solubility of the compound increases with increasing density (ρ) of CO2 fluid, showing a linear… CONTINUE READING

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