Solid-state NMR as a spectroscopic tool for characterizing phosphane-borane frustrated lewis pairs.

Abstract

Frustrated Lewis pair (FLP) chemistry has provided a new strategy for small molecule binding and/or catalytic activation. It is based on the cooperative reaction behavior of Lewis acid and Lewis base centers that are in close proximity to each other (e.g., within the same molecule) but cannot form a direct bond because of geometrical constraints. The most… (More)
DOI: 10.1007/128_2012_386

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