Solid-phase template-directed synthesis of a [2]rotaxane using a solid-phase stopper.

@article{Bravo2002SolidphaseTS,
  title={Solid-phase template-directed synthesis of a [2]rotaxane using a solid-phase stopper.},
  author={Jos{\'e} Antonio Recondo Bravo and David Orain and M. Zamft Bradley},
  journal={Chemical communications},
  year={2002},
  volume={3},
  pages={
          194-5
        }
}
The first synthesis of a rotaxane by solid phase chemistry has been achieved, using the resin bead as a 'Mega' stopper during the synthesis. One of the advantages of this methodology over traditional solution routes include the ability to use mass action to drive the chemistry, without complicating the purification process. 
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