Smooth Continuous Films of Stoichiometric Silicon Carbide from Poly(methylsilyne)

@article{Pitcher2004SmoothCF,
  title={Smooth Continuous Films of Stoichiometric Silicon Carbide from Poly(methylsilyne)},
  author={Michael W. Pitcher and Scott J. Joray and Patrizia Bianconi},
  journal={Advanced Materials},
  year={2004},
  volume={16}
}

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TLDR
An increase in the ceramic yields for irradiated polymers was observed, parallel to a drastic decrease in the soluble polymer synthetic yield, when the polymer irradiation was performed in the presence of AIBN.

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We report a sonochemical process for a single-pot synthesis of high molecular weight poly(methylsilane) (PMS) of composition [(CH3SiH)x(CH3Si)y(CH3SiH2)z]n, where x + y + z = 1 and 0.65 ≥ (x + z) ≥

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On decrit un nouveau precurseur polymere pour fibres de SiC, que l'on peut preparer a partir de matieres premieres peu couteuses. On examine ses spectres RMN, DRIFT et XRD

Borate-Catalyzed Thermolysis of Polymethylsilane

Polymethylsilane (PMS) with a general formula [−(CH3SiH)1-y−(CH3Si)y−]n has been synthesized by Wurtz type polycondensation of methyldichlorosilane. Copolycondensation with dimethylchlorosilane was