Small changes have consequences: lessons from tetrabenzyltitanium and -zirconium surface organometallic chemistry.

Abstract

Homoleptic benzyl derivatives of titanium and zirconium have been grafted onto silica that was dehydroxylated at 200 and 700 °C, thereby affording bi-grafted and mono-grafted single-site species, respectively, as shown by a combination of experimental techniques (IR, MAS NMR, EXAFS, and elemental analysis) and theoretical calculations. Marked differences… (More)
DOI: 10.1002/chem.201202737

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Cite this paper

@article{Popoff2013SmallCH, title={Small changes have consequences: lessons from tetrabenzyltitanium and -zirconium surface organometallic chemistry.}, author={Nicolas Popoff and Jeff Espinas and J{\'e}r{\'e}mie D A Pelletier and Beno{\^i}t Macqueron and Kai Cheung Szeto and Olivier Boyron and Christophe Boisson and Iker del Rosal and Laurent Maron and Aimery de Mallmann and R{\'e}gis M Gauvin and Mostafa Taoufik}, journal={Chemistry}, year={2013}, volume={19 3}, pages={964-73} }