Skeletal Rearrangements of Polycyclic α-Ketols.


It has been proposed that prekinamycin and kinobscurinone may biogenetically isomerize to isoprekinamycin and prefluostatin, respectively, through the corresponding bridgehead α-ketol intermediates. In this transformation, the 6-5 ring system is converted into a 5-6 ring system via an α-ketol rearrangement. In this report, the skeletal rearrangement of… (More)
DOI: 10.1021/acs.orglett.6b03541


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@article{Kawamura2017SkeletalRO, title={Skeletal Rearrangements of Polycyclic α-Ketols.}, author={Moe Kawamura and Shogo Kamo and Shuhei Azuma and Konomi Kubo and Takahiro Sasamori and Norihiro Tokitoh and Kouji Kuramochi and Kazunori Tsubaki}, journal={Organic letters}, year={2017}, volume={19 2}, pages={301-303} }