Site-specific H/D exchange of p-methoxyphenol studied by resonant two-photon ionization and mass-analyzed threshold ionization spectroscopy.

@article{Yuan2005SitespecificHE,
  title={Site-specific H/D exchange of p-methoxyphenol studied by resonant two-photon ionization and mass-analyzed threshold ionization spectroscopy.},
  author={Leyang Yuan and Can Li and Wen Bih Tzeng},
  journal={The journal of physical chemistry. A},
  year={2005},
  volume={109 42},
  pages={9481-7}
}
The origin of the S(1) <-- S(0) transition (E(1)) and the adiabatic ionization energy (IE) of cis-p-methoxyphenol-d(1)-OD are determined to be 33 660 and 62 302 cm(-1), whereas those of cis-p-methoxyphenol-d(1)-OCH(2)D are 33 669 and 62 323 cm(-1), respectively. Similarly, the E(1) and IE of trans-p-methoxyphenol-d(1)-OD are determined to be 33 563 and 62… CONTINUE READING