Single-crystal adsorption calorimetry and density functional theory of CO chemisorption on fcc Co{110}.

@article{Liao2013SinglecrystalAC,
  title={Single-crystal adsorption calorimetry and density functional theory of CO chemisorption on fcc Co\{110\}.},
  author={Kristine Liao and Vittorio Fiorin and David S. D. Gunn and Stephen J Jenkins and David A. King},
  journal={Physical chemistry chemical physics : PCCP},
  year={2013},
  volume={15 11},
  pages={4059-65}
}
Using single-crystal adsorption calorimetry (SCAC) and density functional theory (DFT), the interaction of carbon monoxide on fcc Co{110} is reported for the first time. The results indicate that adsorption is consistent with molecular chemisorption at all coverages. The initial heat of adsorption of 140 kJ mol(-1) is found in the range of heat values… CONTINUE READING