Simplified crossover droplet model for adsorption of pure fluids in slit pores.

Abstract

We present a generalized crossover (GC) model for the excess adsorption of pure fluids at a flat solid-liquid interface, which reproduces scaling behavior of the excess adsorption in the critical region and is reduced to the classical, van der Waals-type analytical model far away from the bulk critical point. In developing this model, we used the density… (More)

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@article{Kiselev2004SimplifiedCD, title={Simplified crossover droplet model for adsorption of pure fluids in slit pores.}, author={Sergei B. Kiselev and Janet Ely}, journal={The Journal of chemical physics}, year={2004}, volume={120 17}, pages={8241-52} }